UN-4.2 Testing
UN-4 criteria govern self-heating behavior, packaging, labeling, and transport of bio-based solids. UN class 4 tests under “Manual of Tests and Criteria” (8th revised edition, 2023) , [section 4.2], applies to substances classified as “self heating”
The data collected classifies a material as SELF HEATING or NON-SELF HEATING, and is essential for assigning the correct UN number/class, packing materials safely, and complying with regulations like SDS, IMDG and ADR. Without it, shippers and producers risk misclassification, fines, delays, or potentially dangerous transport and storage incidents.
Different processes, temperatures, materials and operating conditions can change a materials classification level. A change of 10 degrees C during the production of biochar could drastically alter shipping requirements and leave the manufacturer liable if the SDS or shipping documents are not up to date.
How confident are you in the information on your SDS or MSDS ?


Our UN-4.2 Testing Methodology
ThermaSure Labs testing is carried out in strict accordance with the UN 4 Manual of Tests and Criteria, 8th revised edition, 2023. this document define specific requirements for isothermal forced convection oven testing, specific construction of crucibles, and scaled bulk trials to characterize self-heating and auto-ignition of torrefied materials and biochar. We are committed to delivering reproducible data, clear classifications, and defensible documentation for producers, regulators, insurers, and shippers.

Technical Resources and Downloads
Access current test protocols, sample preparation checklists, sample inventory and shipping information
